Raman Spectra of [N(CH 3 ) 4 ] 2 ZnCl 4  Single Crystals I. Raman Spectra of the Parent Phase | Zendy

Torgashev V. I. | Zendy; Yuzyuk Yu. I. | Zendy; Rabkin L. M. | Zendy; Durnev Yu. I. | Zendy; Latush L. T. | Zendy

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Raman Spectra of [N(CH 3 ) 4 ] 2 ZnCl 4 Single Crystals I. Raman Spectra of the Parent Phase

Author(s) -

Torgashev V. I.,

Yuzyuk Yu. I.,

Rabkin L. M.,

Durnev Yu. I.,

Latush L. T.

Publication year - 1991

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.2221650127

Subject(s) - raman spectroscopy , spectral line , ion , tetrahedron , phase (matter) , materials science , crystallography , chemistry , molecular physics , optics , physics , organic chemistry , astronomy

Polarized Raman spectra of [N(CH 3 ) 4 ] 2 ZnCl 4 crystals are studied in phase I in the frequency range between 10 and 3500 cm −1 . An assignment of the lines observed to motion types is carried out. The sublattice of the TMA ions is found to behave as a quasi‐liquid. The distorsion of the ZnCl 4 2‐tetrahedra is insignificant. A considerable orientational disorder is shown to occur in this phase.

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