An interpretation of the pressure dependence of EPR zero‐field splitting of Mn 2+  in Na 2 ZnCl 4  · 3 H 2 O | Zendy

Lu KeQin | Zendy; Guo ShengLi | Zendy; Wu PingFeng | Zendy

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An interpretation of the pressure dependence of EPR zero‐field splitting of Mn 2+ in Na 2 ZnCl 4 · 3 H 2 O

Author(s) -

Lu KeQin,

Guo ShengLi,

Wu PingFeng

Publication year - 1989

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.2221520219

Subject(s) - zero (linguistics) , interpretation (philosophy) , parametrization (atmospheric modeling) , ion , electron paramagnetic resonance , field (mathematics) , zero field splitting , physics , value (mathematics) , condensed matter physics , chemistry , materials science , mathematics , nuclear magnetic resonance , quantum mechanics , pure mathematics , electron , statistics , philosophy , linguistics , spin polarization , radiative transfer

The relationship between the zero‐field splitting parameter D and the C 3v crystalline potential components for Mn 2+ ions is established by using the parametrization d‐orbital theory proposed by Zhao et al. The pressure dependence of D of Mn 2+ in Na 2 ZnCl 4 · 3 H 2 O is calculated. The results agree well with the values measured experimentally indicate that the D ‐value increase with increasing pressure is caused most dominately by changing in the angle θ and next by the change in the bond length R under pressure.

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