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Spin–Orbit and Crystal‐Field Matrices of d 4,6 Configuration and Application to RbFeCl 3
Author(s) -
WeiLi Shuen,
MinGuang Zhao
Publication year - 1987
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.2221420220
Subject(s) - zeeman effect , field (mathematics) , orbit (dynamics) , symmetry (geometry) , spin–orbit interaction , physics , spin (aerodynamics) , crystal (programming language) , zero field splitting , crystal field theory , atomic physics , condensed matter physics , magnetic field , quantum mechanics , geometry , mathematics , ion , spin polarization , computer science , pure mathematics , engineering , thermodynamics , programming language , aerospace engineering , electron
The spin–orbit and crystal‐field matrices of d 4,6 configuration with C 3v symmetry are derived based on the weak‐field scheme. Utilizing these matrices obtained and the approximate SCF d‐orbit of Fe 2+ proposed by Zhao, the zero‐field splitting, optical absorption bands, and the Zeeman dependences are calculated for RbFeCl 3 . The calculation results agree well with experimental findings.