Spin–Orbit and Crystal‐Field Matrices of d 4,6  Configuration and Application to RbFeCl 3 | Zendy

WeiLi Shuen | Zendy; MinGuang Zhao | Zendy

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Spin–Orbit and Crystal‐Field Matrices of d 4,6 Configuration and Application to RbFeCl 3

Author(s) -

WeiLi Shuen,

MinGuang Zhao

Publication year - 1987

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.2221420220

Subject(s) - zeeman effect , field (mathematics) , orbit (dynamics) , symmetry (geometry) , spin–orbit interaction , physics , spin (aerodynamics) , crystal (programming language) , zero field splitting , crystal field theory , atomic physics , condensed matter physics , magnetic field , quantum mechanics , geometry , mathematics , ion , spin polarization , computer science , pure mathematics , engineering , thermodynamics , programming language , aerospace engineering , electron

The spin–orbit and crystal‐field matrices of d 4,6 configuration with C 3v symmetry are derived based on the weak‐field scheme. Utilizing these matrices obtained and the approximate SCF d‐orbit of Fe 2+ proposed by Zhao, the zero‐field splitting, optical absorption bands, and the Zeeman dependences are calculated for RbFeCl 3 . The calculation results agree well with experimental findings.

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