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Photon‐phonon interaction influence on the external vibration spectra of molecular crystals
Author(s) -
Botvich A. N.,
Shabanov V. F.,
Vtyurin A. N.,
Pozdnyakova T. A.
Publication year - 1986
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.2221340209
Subject(s) - polariton , phonon , photon , resonance (particle physics) , observable , crystal (programming language) , raman spectroscopy , raman scattering , spectral line , condensed matter physics , wave vector , molecular physics , physics , scattering , eigenvalues and eigenvectors , atomic physics , quantum mechanics , computer science , programming language
A method is developed to determine the parameters of electromagnetic and elastic excitations in molecular crystals including the polariton resonance region. The dependence of eigenvectors and eigenfrequencies on the wavevector of elementary excitations is calculated numerically for m‐chloronitrobenzene crystals. The conditions are found when the photon‐phonon resonance effect becomes observable in the Raman scattering (RS) spectra of this crystal.

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