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The ligand field on d n ions in a strained corundum crystal
Author(s) -
Lacroix R.
Publication year - 1986
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.2221330228
Subject(s) - corundum , hamiltonian (control theory) , covalent bond , ion , doping , chemistry , crystal (programming language) , ligand field theory , crystallography , condensed matter physics , physics , materials science , quantum mechanics , mineralogy , mathematics , mathematical optimization , computer science , programming language
The ligand field Hamiltonian for a d electron in a transition metal doping a strained corundum crystal is worked out in the frame of a cluster model. The formulation makes explicit reference to the inner elasticity constants and allows the Hamiltonian to be used as well from the covalent point of view as in the point charge model.