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Solution of the spin‐hamiltonian with orthorhombic HF and g‐tensors (S = 1/2). II. Application to VO 2+ centres in oxide glasses
Author(s) -
Seth V. P.,
Yadav A.,
Bansal R. S.
Publication year - 1986
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.2221330134
Subject(s) - orthorhombic crystal system , hamiltonian (control theory) , ternary operation , boron , oxide , spectral line , spin glass , optical spectra , condensed matter physics , chemistry , materials science , crystallography , inorganic chemistry , analytical chemistry (journal) , physics , quantum mechanics , crystal structure , mathematics , organic chemistry , mathematical optimization , computer science , programming language
A theory developed previously is used in the analysis of ESR spectra of VO 2+ in ternary borate glasses. The theoretical optical basicity of these glasses is calculated. It is found that | P | and | A ′ ‖ | are larger and K is smaller in those glasses for which the optical basicity is large.