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The Contribution of Davydov Solitons to the Value of the Kinetic Coefficient of Electron Transfer along a One‐Dimensional Molecular Chain
Author(s) -
Ivić Z.,
Satarić M.,
Žakula R.
Publication year - 1985
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.2221290122
Subject(s) - kinetic energy , molecule , representation (politics) , electron , chain (unit) , electron transfer , physics , value (mathematics) , transfer (computing) , chemistry , atomic physics , thermodynamics , statistical physics , quantum mechanics , mathematics , statistics , politics , political science , law , parallel computing , computer science
An expression is derived for the kinetic coefficient of the electron transfer from donor molecules (D m ) to acceptor molecules (A l ) along a quasi‐one‐dimensional molecular chain, to which D m and A l are statistically attached. Using the method of the non‐equilibrium statistical mechanics and coherent states representation, the influence is studied of the transfer mechanism of Davydov solitons on the value of the kinetic coefficient.