ESR and Magnetic Investigation of Lithium Intercalated VSe 2 | Zendy

Watanabe Y. | Zendy

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ESR and Magnetic Investigation of Lithium Intercalated VSe 2

Author(s) -

Watanabe Y.

Publication year - 1984

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.2221220136

Subject(s) - ion , vanadium , valence (chemistry) , lithium (medication) , electron paramagnetic resonance , intercalation (chemistry) , magnetic susceptibility , spectral line , materials science , chemistry , inorganic chemistry , analytical chemistry (journal) , crystallography , nuclear magnetic resonance , physics , medicine , organic chemistry , astronomy , endocrinology , chromatography

X‐band ESR spectra are examined during the Li intercalation process of VSe 2 in n‐butyllithium solution. The formation of V 2+ ions at an early stage of reaction and their subsequent partial disappearance are ascertained in the case of solutions where Li contents are totally deficient for the production of Li 2 VSe 2 . The temperature‐dependence of the width of V 2+ ESR lines exhibits a broad minimum around 150 K. This is interpreted in terms of effects of the interaction of V 2+ ions with other vanadium ions in some different valence states.

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