Near‐Infrared d–d Transitions of NiI 2 , CdI 2 :Ni 2+ , and CoI 2 | Zendy

Kuindersma S. R. | Zendy; Boudewijn P. R. | Zendy; Haas C. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Near‐Infrared d–d Transitions of NiI 2 , CdI 2 :Ni 2+ , and CoI 2

Author(s) -

Kuindersma S. R.,

Boudewijn P. R.,

Haas C.

Publication year - 1981

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.2221080122

Subject(s) - ion , spectral line , absorption spectroscopy , absorption (acoustics) , atomic physics , infrared , physics , birefringence , crystal (programming language) , electron , infrared spectroscopy , materials science , condensed matter physics , optics , quantum mechanics , computer science , programming language , astronomy

The absorption spectra of NiI 2 , CdI 2 :Ni 2+ , and CoI 2 in the wave‐number region 4000 to 16000 cm −1 are reported. The spectra are interpreted in terms of d‐d transitions of Ni 2+ and Co 2+ ions. Parameters of the electron repulsion, cubic crystal field, and spin‐orbit coupling are estimated. From the latter the transferred spin densities are deduced and compared with Mössbauer data. Birefringence experiments as a function of the temperature show the presence of two phase transitions in niI 2 .

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research