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d—s, p Resonance and Electronic Structure of Compounds, Alloys, and Solid Solutions
Author(s) -
Domashevskaya E. P.,
Terekhov V. A.
Publication year - 1981
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.2221050113
Subject(s) - valence (chemistry) , electron , electronic structure , resonance (particle physics) , electronic band structure , spectral line , atomic physics , valence band , chemistry , solid state , x ray photoelectron spectroscopy , condensed matter physics , valence electron , physics , nuclear magnetic resonance , quantum mechanics , organic chemistry
On the basis of the valence band structure regularities, obtained from combined X‐ray spectral and X‐ray photoelectron studies of electron energy spectra, a model is suggested for the interaction between valence electrons of s, p‐elements and d‐electrons of IIIA, IIB, IB, and transition metals under the formation of compounds, alloys, and solid solutions, the so called d—s, p resonance. The model qualitatively explains different observed manifestations of state interaction: the energy displacements, subband splitting, mixing of states of different symmetry or, vice versa, pushing of s, p‐states out of the energy interval, occupied by d‐band, due to the mutual energy arrangement of d‐ and s, p‐subbands.