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EPR of Hydrogen and Deuterium Atoms in Alkali Halide Crystals
Author(s) -
Badalyan A. G.,
Baranov P. G.
Publication year - 1980
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.2220970108
Subject(s) - electron paramagnetic resonance , deuterium , hyperfine structure , halide , alkali metal , hydrogen , ion , spectral line , chemistry , crystallography , inorganic chemistry , atomic physics , nuclear magnetic resonance , organic chemistry , physics , astronomy
In RbCl, KBr, and NaCl crystals EPR spectra of anion atoms of hydrogen (H a 0 ) and deuterium (D a 0 ) are obtained and studied after UV irradiation. Hyperfine structure constants and g ‐factors of H a 0and D a 0centres are determined from these spectra. In RbCl resolved structure of the EPR lines of H a 0and D a 0is observed in the orientation H ‖ [100]. The atoms H a 0and D a 0are supposed to occupy off‐centre positions in crystals.