Temperature‐Dependent Mn 2+ ‐ 6 S State Splitting in Scheelites | Zendy

Biederbick R. | Zendy; Hofstaetter A. | Zendy; Scharmann A. | Zendy

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Temperature‐Dependent Mn 2+ ‐ 6 S State Splitting in Scheelites

Author(s) -

Biederbick R.,

Hofstaetter A.,

Scharmann A.

Publication year - 1978

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.2220890214

Subject(s) - atmospheric temperature range , ion , impurity , zero field splitting , atomic physics , physics , electron paramagnetic resonance , cationic polymerization , chemistry , crystallography , nuclear magnetic resonance , thermodynamics , quantum mechanics , electron , organic chemistry , spin polarization

Measurements of the EPR spectrum of seven scheelite structure crystals doped with Mn 2+ ions are performed in the temperature range from 4.2 to 350 K. Experimental data of a preceding paper [1] are completed. The temperature dependent zero field splitting is discussed in terms of implicit and explicit contributions. Being the most important one the temperature effect of b 2 0is described with an Einstein model where the impurity force constant is related to regular cationic vibrations by a Born‐Mayer potential.

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