Electron Spin Resonance of Mobile Electrons in AgCl | Zendy

Eachus R. S. | Zendy; Graves R. E. | Zendy; Olm M. T. | Zendy

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Electron Spin Resonance of Mobile Electrons in AgCl

Author(s) -

Eachus R. S.,

Graves R. E.,

Olm M. T.

Publication year - 1978

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.2220880238

Subject(s) - electron paramagnetic resonance , photoconductivity , impurity , ion , doping , cationic polymerization , electron , materials science , divalent , chemistry , silver chloride , microwave , chloride , charge carrier , photochemistry , analytical chemistry (journal) , inorganic chemistry , nuclear magnetic resonance , optoelectronics , physics , organic chemistry , electrode , quantum mechanics , polymer chemistry , metallurgy , chromatography

Divalent cationic impurities such as Cd 2+ and Pb 2+ and low levels of Br − ions extend the photo‐electron lifetime in silver chloride. The free carrier is observed by conventional ESR in the doped solid, and a free‐electron g ‐value of 1.8775 ± 0.0005 is obtained. A careful correlation of kinetic data obtained by ESR and the ac microwave photoconductivity technique leads to a reasonable mechanism to explain the photoinduced decomposition of the doped material.

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