The phonon induced zero field splitting in vanadium doped alkali chlorides | Zendy

Vanhaelst M. | Zendy; Matthys P. | Zendy; Boesman E. | Zendy

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The phonon induced zero field splitting in vanadium doped alkali chlorides

Author(s) -

Vanhaelst M.,

Matthys P.,

Boesman E.

Publication year - 1978

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.2220850228

Subject(s) - vanadium , alkali metal , doping , hamiltonian (control theory) , phonon , condensed matter physics , anisotropy , zero (linguistics) , zero field splitting , physics , materials science , chemistry , quantum mechanics , inorganic chemistry , mathematics , spin polarization , mathematical optimization , linguistics , philosophy , electron

The zero field splitting in V 2+ doped NaCl, KCl, and RbCl is temperature dependent and has a shallow minimum near 50 K. Previously reported experiments are compared with theoretical results based on an anisotropic continuum phonon model. The qualitative behaviour of the spin‐Hamiltonian constant D as well as the quantitative agreement of the coefficients, which determine D as a function of temperature, are discussed.

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