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On the theory of hyper Raman scattering in molecular crystals
Author(s) -
Zavorotnev Yu. D.,
Ovander L. N.
Publication year - 1975
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.2220680144
Subject(s) - raman scattering , intermolecular force , hamiltonian (control theory) , raman spectroscopy , x ray raman scattering , scattering , polariton , inversion (geology) , transverse plane , physics , photon , molecular physics , crystal (programming language) , condensed matter physics , chemistry , quantum mechanics , molecule , mathematics , mathematical optimization , paleontology , structural engineering , structural basin , computer science , engineering , biology , programming language
Hyper Raman scattering in crystals with an inversion centre is investigated using polariton theory. I n the Hamiltonian of a crystal, terms are taken into account, which are responsible for the intermolecular, kinematic interactions and the interaction of charges with the transverse photon field. The explicit form of the hyper Raman scattering tensor is calculated. For groups with an inversion centre the way of identification of the contribution of the intermolecular interaction to this effect is shown.