Anisotropic Hyperfine Interaction of Pb 3+  Ions in  2 S 1/2 ‐State EPR | Zendy

Born G. | Zendy; Hofstaetter A. | Zendy; Scharmann A. | Zendy; Vitt B. | Zendy

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Anisotropic Hyperfine Interaction of Pb 3+ Ions in 2 S 1/2 ‐State EPR

Author(s) -

Born G.,

Hofstaetter A.,

Scharmann A.,

Vitt B.

Publication year - 1974

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.2220660134

Subject(s) - hyperfine structure , anisotropy , electron paramagnetic resonance , atomic orbital , ion , atomic physics , covalent bond , physics , spectral line , symmetry (geometry) , tensor (intrinsic definition) , chemistry , nuclear magnetic resonance , electron , quantum mechanics , geometry , mathematics

From the angular dependences of EPR‐spectra of the 2 S 1/2 ‐state system Pb 2+ in CaWO 4 an anisotropic hyperfine interaction with the 207 Pb nucleus is inferred. The weak anisotropy (≈1 0 / 00 ) of the hyperfine A ‐tensor is caused by the admixture of covalent ligand orbitals to the central s‐function in D 2d symmetry.

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