Band Structure of K 2 [Pt(CN) 4 ]Br 0.30 ·3H 2 O | Zendy

Zeller H. R. | Zendy; Brüesch P. | Zendy

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Band Structure of K 2 [Pt(CN) 4 ]Br 0.30 ·3H 2 O

Author(s) -

Zeller H. R.,

Brüesch P.

Publication year - 1974

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.2220650212

Subject(s) - electron , oscillator strength , conduction band , physics , instability , atomic physics , condensed matter physics , quantum mechanics , spectral line

Experiments show that except for the Peierls instability the conduction electrons in K 2 [Pt(CN) 4 ]Br 0.30 ·3H 2 O behave as nearly free electrons in the c ‐direction. This is concluded from the optically deduced effective mass m * ≈ m e , from the oscillator strength sum rule and from energy and oscillator strength of the first interband transition. It is shown that this result although unexpected at first sight is a natural consequence of the one‐dimensionality of the system.

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