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Low‐Symmetry Crystal Fields in CrCl 3
Author(s) -
Majer M.,
Szymczak H.
Publication year - 1974
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.2220620241
Subject(s) - trigonal crystal system , symmetry (geometry) , crystal (programming language) , electron paramagnetic resonance , field (mathematics) , rotation (mathematics) , physics , matrix (chemical analysis) , spectral line , spin–orbit interaction , condensed matter physics , materials science , molecular physics , chemistry , crystallography , nuclear magnetic resonance , crystal structure , quantum mechanics , geometry , mathematics , computer science , pure mathematics , programming language , composite material
A crystal field study has been performed for CrCl 3 crystals. The energy matrix has been diagonalized within the 120 states of the complete d 3 configuration. In the calculation the trigonal field, spin–orbit interaction as well as Tree's correction have been taken into account. The results of the calculations have been compared with the experimental data on the specific magnetic rotation, optical absorption, and EPR spectra.