EPR of BaCl 2 :Gd 3+ | Zendy

Oosterhoff T. | Zendy; Den Hartog H. W. | Zendy

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EPR of BaCl 2 :Gd 3+

Author(s) -

Oosterhoff T.,

Den Hartog H. W.

Publication year - 1974

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.2220620216

Subject(s) - orthorhombic crystal system , electron paramagnetic resonance , ion , chemistry , analytical chemistry (journal) , isotropy , crystal (programming language) , materials science , crystallography , nuclear magnetic resonance , crystal structure , physics , optics , chromatography , organic chemistry , programming language , computer science

The g ‐value and the most important crystal field parameters of Gd 3+ in orthorhombic (D 2h 16 ) BaCl 2 , are determined at room temperature: g = 1.994 (isotropic), b 2 0= ± 90 × × 10 −4 cm −1 , and b 2 2= ∓444 × 10 −4 .cm −1 . The corresponding theoretical values are g = 1.993, b 2 0= 85 × 10 −4 cm −1 , and b 2 2= −324 × 10 −4 cm −1 . A comparison of the results with values for Eu 2+ and Gd 3+ ions at Pb 2+ sites in PbCl 2 , and PbBr 2 , is made.

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