Diagonalization of the  g ‐Matrix of Low Symmetry Transition Ions | Zendy

Soliverez C. E. | Zendy; Belorizky E. | Zendy

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Diagonalization of the g ‐Matrix of Low Symmetry Transition Ions

Author(s) -

Soliverez C. E.,

Belorizky E.

Publication year - 1973

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.2220580215

Subject(s) - zeeman effect , hamiltonian (control theory) , symmetry (geometry) , matrix (chemical analysis) , physics , basis (linear algebra) , magnetic field , rotation (mathematics) , hamiltonian matrix , mathematical physics , mathematics , quantum mechanics , symmetric matrix , chemistry , geometry , eigenvalues and eigenvectors , mathematical optimization , chromatography

The explicit operations — rotation of coordinate axes and transformation of basis functions — required in order to diagonalize the g ‐matrix of a Zeeman spin‐Hamiltonian linear with respect to the magnetic field and the effective spin operators, are given for low symmetry complexes. The case where the g ‐matrix is singular, is carefully analyzed.

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