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EPR Spectra of Transition Element Impurities with 3d 2 Configuration in Hexagonal CdS and CdSe Single Crystals
Author(s) -
Böttcher R.,
Dziesiaty J.
Publication year - 1973
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.2220570219
Subject(s) - electron paramagnetic resonance , wurtzite crystal structure , impurity , cadmium selenide , crystallography , hexagonal crystal system , materials science , cadmium , paramagnetism , condensed matter physics , spectral line , chemistry , nuclear magnetic resonance , physics , nanotechnology , organic chemistry , quantum dot , astronomy , metallurgy
Electron paramagnetic resonance has been studied for divalent titanium with 3d 2 configuration substituting for Cd in hexagonal single crystals of cadmium sulphide and cadmium selenide. The parameters of the spin‐Hamiltonian have been determined at T = 27 and 77 K. It is found that the symmetry of the centre is axial, corresponding to the C 3V symmetry of an isolated impurity on normal lattice sites in wurtzite.