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Photographic study of the zeeman effect in the satellite structure of praseodymium double nitrates
Author(s) -
Douglas I. N.
Publication year - 1971
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.2220480131
Subject(s) - praseodymium , zeeman effect , impurity , manganese , zinc , chemistry , ion , magnetic field , spectral line , perturbation (astronomy) , inorganic chemistry , physics , quantum mechanics , organic chemistry
Satellites associated with the praseodymium transitions in thc spectra of solid solutions of manganese and zinc double nitrates, Pr 2 Mn 3 ‐ x Zn x (NO 3 ) 12 · 24 H 2 O, have been observed, and their behaviour in an axial magnetic field has been investigated photographically at 4.2 °K. These satellites are explained in terms of the crystal field perturbation due to an impurity bivalent ion, and parameters describing this effect are derived.