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A theoretical calculation of the orbital g ‐factor of the excited state of F‐centres in alkali halides
Author(s) -
Thuau M.,
Margerie J.
Publication year - 1971
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.2220470135
Subject(s) - excited state , halide , alkali metal , wave function , envelope (radar) , chemistry , atomic physics , physics , inorganic chemistry , organic chemistry , telecommunications , radar , computer science
Using a model similar to that of Smith [4] the orbital g ‐factor g orb. of the excited state of F‐centres in LiF, LiCl, NaF, NaCl, KF, and KCl was calculated. The results are quite sensitive to the particular envelope wavefunction chosen for the F‐centre. Gourary and Adrian type II wavefunctions lead to results which are in good agreement with the available experimental values.