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Magnetic circular dichroism of resolved vibronic lines in Cs 2 ZrCl 6 :U 4+
Author(s) -
Piepho S. B.,
Dickinson J. R.,
Schatz P. N.
Publication year - 1971
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.2220470128
Subject(s) - zeeman effect , magnetic circular dichroism , vibronic spectroscopy , circular dichroism , chemistry , atomic physics , dichroism , helium , physics , crystallography , excited state , spectral line , magnetic field , optics , quantum mechanics , astronomy
Magnetic circular dichroism (MCD) measurements at liquid helium temperature are reported for several resolved f–f vibronic lines of U 4+ centres in Cs 2 ZrCl 6 . Though these lines are too broad for Zeeman measurements, both the signs and magnitudes of the g ‐values are determined from the MCD data using first‐order theory. Some assignments are also suggested on the basis of these data.