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The relation between the isotope effect for diffusion and the correlation factor in systems lacking a two‐fold symmetry around the tracer jump vector
Author(s) -
Bakker H.
Publication year - 1971
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.2220440138
Subject(s) - tracer , jump , impurity , diffusion , vacancy defect , isotope , lattice (music) , condensed matter physics , physics , anomalous diffusion , symmetry (geometry) , chemistry , mathematics , thermodynamics , nuclear physics , geometry , quantum mechanics , knowledge management , innovation diffusion , computer science , acoustics
It is investigated under which conditions the isotope effect, E , and the correlation factor, f , for diffusion by means of complex lattice defects (lacking a two‐fold symmetry around the tracer‐defect jump vector) are connected by E = f Δ K . In particular it is shown, that the conditions are fulfilled for (impurity) diffusion by divacancies and for diffusion by vacancy‐impurity pairs in f.c.c. metals.

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