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Local Structure Analysis around Ti in Lead Zirconate Titanate by X‐Ray Fluorescence Holography
Author(s) -
Hayashi Kouichi,
Lu Cong,
Ang Artoni Kevin R.,
Ohwada Kenji,
Xie Yujuan,
Hu Wen,
Matsushita Tomohiro,
Happo Naohisa,
Hosokawa Shinya,
Bokov Alexei A.,
Ye Zuo-Guang
Publication year - 2020
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.202000191
Subject(s) - lead zirconate titanate , materials science , ferroelectricity , dielectric , piezoelectricity , holography , crystal structure , diffraction , crystal (programming language) , optics , mineralogy , crystallography , optoelectronics , chemistry , physics , composite material , programming language , computer science
To clarify the mechanism of ferroelectricity in lead zirconate titanate (PZT), the local structure around Ti in a Pb(Zr 0.7 Ti 0.3 )O 3 single crystal is investigated using X‐ray fluorescence holography. The raw hologram data are contaminated by periodic noise due to the fluctuation of the incident X‐ray intensity. The periodical noise is successfully removed using an inverse Fourier transformation method. From the filtered holograms, the atomic images around Ti can be reconstructed clearly. The reconstructions of B‐site cations demonstrate an outward displacement of the neighboring Ti from the ideal B‐site position, indicating an expansion of the local lattice around Ti. In addition, the splitting of Pb images is found, and the relative displacement between Ti and Pb atoms is deduced. These results contribute to the understanding of the local structure of PZT and can reveal the microscopic origins of very high dielectric and piezoelectric responses, which are essential for designing new and improved ferroelectric materials.