Magnetic properties in metal‐organic framework compounds [M 2 (C 8 H 4 O 4 ) 2  · C 6 H 12 N 2 ] (M = Cu, Ni, Co) | Zendy

Kozlova Svetlana G. | Zendy; Samsonenko Denis G. | Zendy; Tkachenko Ivan A. | Zendy; Slobodyuk Arseny B. | Zendy; Stepnov Dmitrii A. | Zendy; Yunoshev Alexander S. | Zendy

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Magnetic properties in metal‐organic framework compounds [M 2 (C 8 H 4 O 4 ) 2 · C 6 H 12 N 2 ] (M = Cu, Ni, Co)

Author(s) -

Kozlova Svetlana G.,

Samsonenko Denis G.,

Tkachenko Ivan A.,

Slobodyuk Arseny B.,

Stepnov Dmitrii A.,

Yunoshev Alexander S.

Publication year - 2016

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.201600305

Subject(s) - antiferromagnetism , dabco , magnetic susceptibility , ferromagnetism , octane , metal , magic angle spinning , materials science , ion , metal organic framework , nuclear magnetic resonance spectroscopy , exchange interaction , chemistry , nuclear magnetic resonance , crystallography , analytical chemistry (journal) , condensed matter physics , stereochemistry , physics , organic chemistry , adsorption

The magnetic properties of metal‐organic framework compounds [M 2 (C 8 H 4 O 4 ) 2 · C 6 H 12 N 2 ] (M = Cu, Ni, Co) were studied in the region of 300–4 K by magnetic susceptibility and 1 H magic‐angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy. The interaction between the magnetic ions M was found to be antiferromagnetic at the temperatures above 100–150 K. Lowering the temperature changes the interaction character to ferromagnetic. The exchange interaction was found between 1,4‐diazabicyclo[2,2,2]octane (dabco) molecules and magnetic ion. Magnetic properties in metal‐organic framework compound.

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