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Symmetry breaking and low energy conformational fluctuations in amorphous graphene
Author(s) -
Li Y.,
Drabold D. A.
Publication year - 2013
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.201248481
Subject(s) - amorphous solid , planar , graphene , symmetry (geometry) , amorphous silicon , physics , atom (system on chip) , relaxation (psychology) , topology (electrical circuits) , symmetry breaking , materials science , condensed matter physics , silicon , chemical physics , nanotechnology , crystalline silicon , chemistry , crystallography , computer science , quantum mechanics , geometry , mathematics , optoelectronics , psychology , social psychology , computer graphics (images) , combinatorics , embedded system
Recently, the prospects for amorphous phases of graphene (α‐g) have been explored computationally. Initial models were flat, and contained odd‐member rings, while maintaining threefold coordination and sp 2 bonding. Upon relaxation, puckering occurs, and may be traced to the existence of pentagons, in analogy with the situation for fullerenes. In this work, we systematically explore the inherent structures with energy close to the flat starting structure. As expected, the planar symmetry can be broken in various ways, which we characterize for 800‐atom model of α‐g, always using local basis density functional techniques. The classical normal modes of various structural models are discussed, with an emphasis on imaginary modes indicating the evolution from flat to puckered. We also discuss very low energy conformational fluctuations akin to those seen previously in amorphous silicon, and reflect on the nature of the amorphous “ground state” within a network of fixed topology. For completeness, high energy modes were also computed, and are found to be associated with strained parts of the network.