Theoretical studies of EPR  g  ‐factors and microstructure of the two tetragonal palladium centers in silver chloride | Zendy

Feng W. L. | Zendy

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Theoretical studies of EPR g ‐factors and microstructure of the two tetragonal palladium centers in silver chloride

Author(s) -

Feng W. L.

Publication year - 2009

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.200945131

Subject(s) - tetragonal crystal system , electron paramagnetic resonance , palladium , impurity , ion , chloride , chemistry , microstructure , crystallography , silver chloride , crystal structure , nuclear magnetic resonance , physics , catalysis , organic chemistry , electrode

The EPR g ‐factors g ∥ , g ⊥ for two tetragonal Pd + impurity centers (i.e. Pd + I and II centers) in AgCl crystal are calculated by using the high‐order perturbation formulas of EPR parameters for the 4d 9 ion in tetragonal symmetry with the ground state |d x 2 – y 2〉. Based on the calculations, the defect models for the two centers are suggested as a substitutional Ag + ion with (PdCl 6 ) 5– or the [(PdCl 6 ) 5– – V Ag +] cluster. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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