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Stability and electronic properties of magnetic peapods
Author(s) -
Tóth S.,
Quintavalle D.,
Náfrádi B.,
Forró L.,
Korecz L.,
Rockenbauer A.,
Kálai T.,
Hideg K.,
Simon F.
Publication year - 2008
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.200879652
Subject(s) - fullerene , pyridine , electron paramagnetic resonance , molecule , nitroxide mediated radical polymerization , materials science , spin (aerodynamics) , nitrogen , chemical physics , nanotechnology , chemistry , nuclear magnetic resonance , organic chemistry , physics , polymer , thermodynamics , radical polymerization , copolymer , composite material
Abstract We report on the temperature stability of N@C 60 peapods using electron spin resonance. The atomic nitrogen escapes at higher temperatures in the peapod than in the crystalline form. We also report on the synthesis of novel magnetic fullerene peapod, a fullerene with an attached pyridine‐nitroxide spin‐label. This molecule can be the ultimate inner spin label for the SWCNTs as it is available in microscopic amounts and is not air sensitive. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)