EPR of V Hal  centres in SrS | Zendy

Seeman V. | Zendy; Danilkin M. | Zendy; Must M. | Zendy; Ots A. | Zendy; Pärnoja E. | Zendy; Pung L. | Zendy; Tarkpea K. | Zendy

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EPR of V Hal centres in SrS

Author(s) -

Seeman V.,

Danilkin M.,

Must M.,

Ots A.,

Pärnoja E.,

Pung L.,

Tarkpea K.

Publication year - 2006

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.200642033

Subject(s) - halogen , electron paramagnetic resonance , ion , vacancy defect , chemistry , doping , inorganic chemistry , analytical chemistry (journal) , crystallography , materials science , nuclear magnetic resonance , organic chemistry , optoelectronics , physics , alkyl

V Hal centres were studied by EPR in SrS doped with halogens after X‐raying the samples at 77 K. V Hal centre arises when a hole is captured by sulphide‐ion next to a cation vacancy with a halogen ion substituting the opposite sulphide‐ion. EPR parameters and thermal decay characteristics are measured for V Cl , V Br , and V I centres. The efficiency of different halogens to produce and stabilise cation vacancies is shown to vary for different alkaline earth sulphides. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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