The origin of low‐dimensional magnetism in Cu( en  ) 2 Pt(CN) 4 | Zendy

Tibenská K. | Zendy; Orendáčová A. | Zendy; Čižmár E. | Zendy; Park J.H. | Zendy; Lančarič Š. | Zendy; Orendáč M. | Zendy; Anders A. G. | Zendy; Vavra M. | Zendy; Potočňák I. | Zendy; Feher A. | Zendy; Meisel M. W. | Zendy

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The origin of low‐dimensional magnetism in Cu( en ) 2 Pt(CN) 4

Author(s) -

Tibenská K.,

Orendáčová A.,

Čižmár E.,

Park J.H.,

Lančarič Š.,

Orendáč M.,

Anders A. G.,

Vavra M.,

Potočňák I.,

Feher A.,

Meisel M. W.

Publication year - 2006

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.200562505

Subject(s) - magnetism , magnetization , electron paramagnetic resonance , condensed matter physics , chemistry , paramagnetism , laser linewidth , ground state , spectral line , relaxation (psychology) , ion , magnetic susceptibility , spin (aerodynamics) , coupling (piping) , nuclear magnetic resonance , physics , materials science , atomic physics , magnetic field , psychology , social psychology , laser , organic chemistry , quantum mechanics , astronomy , optics , thermodynamics , metallurgy

Magneto‐structural correlations in Cu( en ) 2 Pt(CN) 4 ( en = C 2 H 8 N 2 ) have been investigated by experimental studies of the magnetic properties and hydrogen bond geometry. The analysis of electron paramagnetic resonance spectra confirmed the d z 2 electronic ground state of Cu(II) ion expected from room temperature X‐ray measurements. Magnetization and susceptibility data indicate the presence of weak exchange coupling J / k B = –0.4 K. Consequently, a spin diffusive regime in the spin relaxation can be expected at 4 K, and the angular dependence of the linewidth can be qualitatively explained by considering two‐dimensional magnetic behaviour. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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