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Magnetic properties of TM 3 [Cr(CN) 6 ] 2 · n H 2 O
Author(s) -
Zentková M.,
Mihalik M.,
Kováč J.,
Zentko A.,
Mitróová Z.,
Lukáčová M.,
Kavečanský V.,
Kiss L. F.
Publication year - 2006
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.200562463
Subject(s) - antiferromagnetism , magnetization , ferromagnetism , prussian blue , character (mathematics) , atomic force microscopy , crystallography , chemistry , exchange interaction , materials science , analytical chemistry (journal) , condensed matter physics , physics , magnetic field , nanotechnology , geometry , mathematics , electrode , quantum mechanics , chromatography , electrochemistry
Magnetization measurements performed on Prussian blue analogs TM 2+ 3 [Cr III (CN) 6 ] 2 · n H 2 O (TM = Cr, Mn, Fe, Co, Ni, Cu) confirmed the dual character of the exchange interaction (antiferromagnetic AFM and ferromagnetic FM) in this system. AFM interaction dominates for the Cr 2+ sample and with rising atomic number Z the FM interaction becomes more important reaching pure FM character for the Cu 2+ sample. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)