Magnetic properties of TM 3 [Cr(CN) 6 ] 2  ·  n  H 2 O | Zendy

Zentková M. | Zendy; Mihalik M. | Zendy; Kováč J. | Zendy; Zentko A. | Zendy; Mitróová Z. | Zendy; Lukáčová M. | Zendy; Kavečanský V. | Zendy; Kiss L. F. | Zendy

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Magnetic properties of TM 3 [Cr(CN) 6 ] 2 · n H 2 O

Author(s) -

Zentková M.,

Mihalik M.,

Kováč J.,

Zentko A.,

Mitróová Z.,

Lukáčová M.,

Kavečanský V.,

Kiss L. F.

Publication year - 2006

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.200562463

Subject(s) - antiferromagnetism , magnetization , ferromagnetism , prussian blue , character (mathematics) , atomic force microscopy , crystallography , chemistry , exchange interaction , materials science , analytical chemistry (journal) , condensed matter physics , physics , magnetic field , nanotechnology , geometry , mathematics , electrode , quantum mechanics , chromatography , electrochemistry

Magnetization measurements performed on Prussian blue analogs TM 2+ 3 [Cr III (CN) 6 ] 2 · n H 2 O (TM = Cr, Mn, Fe, Co, Ni, Cu) confirmed the dual character of the exchange interaction (antiferromagnetic AFM and ferromagnetic FM) in this system. AFM interaction dominates for the Cr 2+ sample and with rising atomic number Z the FM interaction becomes more important reaching pure FM character for the Cu 2+ sample. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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