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Structural and magnetic properties of Fe 0.45 Mn 0.25 Al 0.30 alloys prepared by mechanical alloying
Author(s) -
Medina M. H.,
Alcázar G. A. Pérez
Publication year - 2006
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.200541342
Subject(s) - paramagnetism , analytical chemistry (journal) , hyperfine structure , materials science , mössbauer spectroscopy , ternary operation , solid solution , ferromagnetism , spin glass , crystallography , chemistry , metallurgy , condensed matter physics , physics , chromatography , quantum mechanics , computer science , programming language
Samples from the Fe 0.45 Mn 0.25 Al 0.30 system were prepared by mechanical alloying during 4, 8, 12, 16, 22 and 24 h by using two different powder‐mass‐to‐ball‐mass ratios of: 1:7.5 and 1:4. X‐ray diffraction (XRD) characterization reveled that samples with 1:7.5 ratios consolidate in a ternary Fe–Mn–Al α‐Fe solid solution at 8 h (chemical mixing time) and those with 1:4 ratios after more than 12 h milling. Mössbauer effect studies (MS) in conjunction with XRD studies show, in samples with a 1:7.5 ratio, a paramagnetic site and a hyperfine field distribution (HFD) for 4 h and only a paramagnetic site for 8 h or more. Therefore, the solid solution is paramagnetic in the stable state. Similar results were obtained for 1:4 ratios, but the paramagnetic site was observed after 16 h or more. Mössbauer studies at low temperatures of the sample milled for 12 h and a 1:4 ratio demonstrate that this sample presents a re‐entrant spin‐glass to the ferromagnetic transition (RSG–F) at T k = 45 K. This RSG–F transition was proven by an ac magnetic susceptibility measurement, appearing at T = 30 K. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)