Comment on “Orbital ordering and orbital fluctuations in transition metal oxides” [phys. stat. sol. (b)  236 , No. 2, 281–288 (2003)] | Zendy

Radwanski R. J. | Zendy; Ropka Z. | Zendy

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Comment on “Orbital ordering and orbital fluctuations in transition metal oxides” [phys. stat. sol. (b) 236 , No. 2, 281–288 (2003)]

Author(s) -

Radwanski R. J.,

Ropka Z.

Publication year - 2005

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.200402124

Subject(s) - condensed matter physics , ion , lattice (music) , degeneracy (biology) , chemistry , ground state , physics , crystallography , atomic physics , quantum mechanics , bioinformatics , acoustics , biology

We argue that the 3 A 2 state considered by Oleś in phys. stat. sol. (b) 236 , 281 (2003) for the d 2 system occurring in the V 3+ ion in V 2 O 3 and LaVO 3 as well as in the Ti 2+ ion in TiO and in many other oxides is wrong. The proper ground state is 3 T 1 g – its 9‐fold degeneracy is further split in a crystal by intra‐atomic spin–orbit interactions and lattice distortions. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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