A covalent model of the optical spectra and EPR parameters for CdS:Ti 2+ | Zendy

Chen JiaJun | Zendy; Du MaoLu | Zendy

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A covalent model of the optical spectra and EPR parameters for CdS:Ti 2+

Author(s) -

Chen JiaJun,

Du MaoLu

Publication year - 2004

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.200402090

Subject(s) - covalent bond , electron paramagnetic resonance , optical spectra , ion , spectral line , symmetry (geometry) , ground state , chemistry , field (mathematics) , physics , atomic physics , molecular physics , condensed matter physics , materials science , nuclear magnetic resonance , quantum mechanics , mathematics , geometry , pure mathematics

In this paper, formulas for the optical spectrum and the EPR parameters calculated for d 2 ions in T d symmetry are established by using a covalent model, in which the covalence contribution has been considered. Using the model, we have calculated the optical spectra and the ground‐state gyromagnetic factor and zero‐field splitting of CdS:Ti 2+ . The calculated results could explain well the experimental findings. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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