Optical properties of Sm‐chelate containing methyl methacryate solution and its solid polymer matrix | Zendy

Liang Hao | Zendy; Zheng Zhiqiang | Zendy; Zhang Qijin | Zendy; Ming Hai | Zendy; Chen Biao | Zendy

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Optical properties of Sm‐chelate containing methyl methacryate solution and its solid polymer matrix

Author(s) -

Liang Hao,

Zheng Zhiqiang,

Zhang Qijin,

Ming Hai,

Chen Biao

Publication year - 2004

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.200301994

Subject(s) - polymer , chelation , solid solution , matrix (chemical analysis) , absorption spectroscopy , materials science , radiative transfer , analytical chemistry (journal) , spectral line , polymer chemistry , chemistry , nuclear chemistry , inorganic chemistry , physics , organic chemistry , optics , composite material , quantum mechanics

From optical absorption spectra and using the Judd–Ofelt theory, the phenomenological parameters, Ω 2 , Ω 4 , and Ω 6 of Sm(DBM) 3 (TOPO) 2 containing methyl methacryate (MMA) solution and solid poly(methyl methacryate) (PMMA) matrix were obtained. The chemical structure of Sm‐chelate accounts for the nearly same Ω 2 values in liquid solution and solid polymer matrix. The evaluation of the radiative properties of Sm‐chelate containing PMMA showed that the 4 G 5/2 → 6 H 9/2 transition of Sm 3+ in polymer matrix is potential to be a laser transition.. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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