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Interpretation of the optical spectra and EPR parameters for Yb 3+ in LiYF 4 crystal
Author(s) -
Dong H. N.,
Zheng W. C.,
Wu S. Y.
Publication year - 2003
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.200301859
Subject(s) - electron paramagnetic resonance , hyperfine structure , crystal (programming language) , interpretation (philosophy) , spectral line , crystal field theory , chemistry , isotope , field (mathematics) , crystallography , materials science , atomic physics , nuclear magnetic resonance , physics , mathematics , ion , quantum mechanics , organic chemistry , computer science , pure mathematics , programming language
In this paper, the crystal‐field energy levels, the EPR g ‐factors g ∥ , g ⟂ of Yb 3+ and hyperfine structure constants A ∥ , A ⟂ of 171 Yb 3+ and 173 Yb 3+ isotopes in LiYF 4 crystal are calculated from the crystal‐field theory. All the calculated results (seven energy levels and six EPR parameters) are in reasonable agreement with the observed values. (© 2003 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)