Premium
X‐ray study of the polarization of the Cu‐cations in CuBr
Author(s) -
Almukhametov R. F.,
Yakshibayev R. A.,
Abdullin A. R.,
Kutusheva R. M.
Publication year - 2003
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.200301650
Subject(s) - copper , polarization (electrochemistry) , tetrahedron , chemistry , electric field , conductor , redistribution (election) , cationic polymerization , crystallography , atomic physics , materials science , physics , organic chemistry , quantum mechanics , politics , political science , law , composite material
The intensities of the X‐ray lines for Cu + ‐cationic conductor CuBr were studied depending on polarization under an electric field. The regular variation in the intensity depending on direction as well as polarization degree was established. A satisfactory agreement was shown for experimental integral intensities depending on copper cation number in the unit cell and those calculated obtained under the condition that all the Cu‐cations in the unit cell are mobile and occupy the tetrahedral sites. The redistribution of the copper cations on tetrahedral sites under the polarization electric field was established.