Isomeric Shifts in Some Tellurium (IV) Isoelectronic Complexes | Zendy

Gukasyan S. E. | Zendy; Iofa B. Z. | Zendy; Karasev A. N. | Zendy; Semenov S. I. | Zendy; Shpinel V. S. | Zendy

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Isomeric Shifts in Some Tellurium (IV) Isoelectronic Complexes

Author(s) -

Gukasyan S. E.,

Iofa B. Z.,

Karasev A. N.,

Semenov S. I.,

Shpinel V. S.

Publication year - 1970

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.19700370111

Subject(s) - electronegativity , tellurium , chemistry , valence electron , valence (chemistry) , crystallography , electron , mössbauer spectroscopy , ligand (biochemistry) , inorganic chemistry , physics , organic chemistry , biochemistry , receptor , quantum mechanics

The Mössbauer effect of the 35.5 keV transition in Te 125 has been studied in Me 2 I [Te IV Hal 6 ] type compounds. The dependence of the isomeric shift on ligand electronegativity has been found to disagree with the behaviour expected from the positive sign of Δ R / R established for Te 125 . Such disagreement can be explained by the presence of an unshared pair of electrons on the valence shell of the four‐valent tellurium in the compounds studied.

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