Paramagnetic Resonance of γ‐Irradiated N 2 H 6 SO 4  and N 2 D 6 SO 4  Single Crystals | Zendy

Barbur I. | Zendy

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Paramagnetic Resonance of γ‐Irradiated N 2 H 6 SO 4 and N 2 D 6 SO 4 Single Crystals

Author(s) -

Barbur I.

Publication year - 1969

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.19690340233

Subject(s) - electron paramagnetic resonance , crystallography , irradiation , resonance (particle physics) , paramagnetism , materials science , crystallographic defect , nuclear magnetic resonance , chemistry , physics , atomic physics , condensed matter physics , nuclear physics

An ESR study was made of defects produced by γ‐irradiation in hydrazonium sulphate (N 2 H 6 SO 4 and N 2 D 6 SO 4 ). The analysis of the experimental data shows that N 2 H 5 +and N 2 D 5 +defects are formed. The mechanism of the appearance of these defects is a breakage of N–H and N–D bonds, respectively. Some remarks about the character of the singly occupied orbital are made.

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