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Paramagnetic Resonance of γ‐Irradiated N 2 H 6 SO 4 and N 2 D 6 SO 4 Single Crystals
Author(s) -
Barbur I.
Publication year - 1969
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.19690340233
Subject(s) - electron paramagnetic resonance , crystallography , irradiation , resonance (particle physics) , paramagnetism , materials science , crystallographic defect , nuclear magnetic resonance , chemistry , physics , atomic physics , condensed matter physics , nuclear physics
An ESR study was made of defects produced by γ‐irradiation in hydrazonium sulphate (N 2 H 6 SO 4 and N 2 D 6 SO 4 ). The analysis of the experimental data shows that N 2 H 5 +and N 2 D 5 +defects are formed. The mechanism of the appearance of these defects is a breakage of N–H and N–D bonds, respectively. Some remarks about the character of the singly occupied orbital are made.