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Electric Field Effect on the ground State Splitting of Mn ++ Ions in NaCl Measured by EPR
Author(s) -
Dreybrodt W.,
Pfister G.
Publication year - 1969
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.19690340107
Subject(s) - ground state , electric field , dipole , ion , electron paramagnetic resonance , tensor (intrinsic definition) , chemistry , atomic physics , electric dipole moment , field (mathematics) , magnetic dipole , state (computer science) , charge (physics) , physics , analytical chemistry (journal) , condensed matter physics , nuclear magnetic resonance , organic chemistry , quantum mechanics , chromatography , pure mathematics , algorithm , computer science , mathematics
Abstract The influence of electric fields on the splitting of the 6 S 5/2 Mn ++ ground state is investigated in NaCl on two centres with charge compensating cation vancancy. The change of the ground state splitting is described by Σ R i j k S i S j F k . The tensor components R i j k are determined. Electric‐field‐induced orientation effects of the dipole moment of the centre with n.n. cation vacancy enable us to determine the signs of the tensor components R i j k .