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Paramagnetic Resonance Spectrum of Gadolinium in CdWO 4 Single Crystals
Author(s) -
Kratêna L.,
Žďánský K.,
Šik V.
Publication year - 1968
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.19680280118
Subject(s) - gadolinium , paramagnetism , nuclear magnetic resonance , electron paramagnetic resonance , resonance (particle physics) , materials science , chemistry , atomic physics , physics , condensed matter physics , metallurgy
The paramagnetic resonance spectrum of Gd 3+ in CdWO 4 is measured at 24 GHz at room temperature. The parameters of the spin Hamiltonian are determined by fitting of the angular dependence of the spectrum. The values of the zero‐field splitting of Gd 3+ and Mn 2+ in CdWO 4 and CaWO 4 are compared and an appropriate mechanism for explaining these values is discussed.