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EPR Study of Cu 2+ Ion in Triglycine Fluoroberyllate
Author(s) -
Stankowski J.
Publication year - 1967
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.19670240206
Subject(s) - electron paramagnetic resonance , ion , ferroelectricity , curie temperature , chemistry , copper , triglycine sulfate , nuclear magnetic resonance , curie , materials science , condensed matter physics , analytical chemistry (journal) , dielectric , physics , ferromagnetism , optoelectronics , organic chemistry , chromatography
An investigation is made of the EPR spectrum of Cu 2+ ions in ferroelectric triglycine fluoroberyllate. The values g∥ = 2.24 g∥ = 2.06, and A = 132 cm −1 are similar to those obtained for copper ions in triglycine sulphate and diglycine nitrate. The new lines are typical of S = 1 and the spectrum is found to have an anomaly at the Curie point. The D parameter of the spectrum is linearly dependent on the spontaneous polarization changes.