Some Results Concerning the Co ++  Site Symmetry in Alkali Halide Crystals | Zendy

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Some Results Concerning the Co ++ Site Symmetry in Alkali Halide Crystals

Author(s) -

Musa M.

Publication year - 1966

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.19660160244

Subject(s) - halide , alkali metal , octahedral symmetry , octahedron , symmetry (geometry) , tetrahedral symmetry , crystallography , chemistry , tetrahedron , ion , inorganic chemistry , spectral line , crystal structure , physics , geometry , mathematics , organic chemistry , astronomy , mechanics , rotational symmetry

Spectral studies are made of the Co ++ ion site symmetry in LiCl and KBr host lattices. It is found that in LiCl and KBr the Co ++ ion symmetry is octahedral and tetrahedral respectively. This conclusion is supported by a comparison with CoCl 2 , Cs 3 CoCl 5 , and Cs 2 CoBr 4 spectra. More detailed structures are found in the spectrum of a RbClCo(Zn)Cl 2 sample as compared with those exhibited by RbClCo ++ single crystals grown from melt.

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