EPR Measurements on Diatomic Halogen Centers in Alkali Halides | Zendy

Dreybrodt W. | Zendy; Silber D. | Zendy

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EPR Measurements on Diatomic Halogen Centers in Alkali Halides

Author(s) -

Dreybrodt W.,

Silber D.

Publication year - 1966

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.19660160121

Subject(s) - diatomic molecule , halide , halogen , alkali metal , electron paramagnetic resonance , chemistry , spectral line , hamiltonian (control theory) , atomic physics , physics , inorganic chemistry , nuclear magnetic resonance , quantum mechanics , molecule , organic chemistry , mathematics , alkyl , mathematical optimization

EPR spectra of diatomic halogen centers in alkali halides are investigated. Centers of the type FBr − , FJ − , and CIJ − are identified. The constants of the spin Hamiltonian are derived from the FBr‐ spectra by a perturbation calculation up to fourth order. By studying the photochemical properties of centers of the type X 2 −and XY − information regarding the formation mechanismus of the FCl − and FBr − centers are obtained.

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