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The Effect of Pressure on a Solid‐Solid Reaction
Author(s) -
Bradley R. S.
Publication year - 1965
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.19650080115
Subject(s) - solid state , diamond , transition state theory , graphite , materials science , thermodynamics , solid solution , density functional theory , chemistry , computational chemistry , kinetics , physics , quantum mechanics , metallurgy , reaction rate constant
Abstract The effect of pressure on a solid‐solid reaction is formulated on a vapour‐gap theory and is compared with the predictions of the transition state theory and of the theory of Teller. The vapour‐gap theory is shown to be inapplicable to the conversion of diamond to graphite.