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CsPbBr 3 Perovskite–Coated Paper Substrate for the Cost‐Effective Detection of Fluoride, Chloride, and Iodide Ions in Water
Author(s) -
Sandeep K.,
Hamida K. T.
Publication year - 2021
Publication title -
physica status solidi (a)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.532
H-Index - 104
eISSN - 1862-6319
pISSN - 1862-6300
DOI - 10.1002/pssa.202100101
Subject(s) - iodide , halide , fluoride , chloride , inorganic chemistry , ion , chemistry , substrate (aquarium) , ion exchange , perovskite (structure) , materials science , organic chemistry , oceanography , geology
Developing a simple and cost‐effective substrate for the detection of the halide ions present in water is extremely important due to their adverse effects at higher concentrations. A good substrate should behave differently in the presence of different halide ions. Herein, a CsPbBr 3 ‐coated paper substrate is used for the detection of fluoride, chloride, and iodide ions. As a result of the fast anion exchange reactions, in the presence of each halide ion, the CsPbBr 3 ‐coated paper shows different emission behaviors. The presence of chloride and iodide ions results in blueshifted and redshifted absorption and emission, respectively. In the presence of fluoride ions, anion exchange followed by decomposition of the perovskite nanocrystal is observed. The anion exchange reactions of CsPbBr 3 perovskites are faster than the moisture‐induced decomposition, which enables the detection of micromolar concentrations of fluoride, chloride, and iodide ions in water.

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