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Interplay of Performance‐Limiting Nanoscale Features in Cu 2 ZnSn(S,Se) 4 Solar Cells
Author(s) -
Ritzer Maurizio,
Schönherr Sven,
Schöppe Philipp,
Larramona Gerardo,
Choné Christophe,
Gurieva Galina,
Johannes Andreas,
Ritter Konrad,
Martínez-Criado Gema,
Schorr Susan,
Ronning Carsten,
Schnohr Claudia S.
Publication year - 2020
Publication title -
physica status solidi (a)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.532
H-Index - 104
eISSN - 1862-6319
pISSN - 1862-6300
DOI - 10.1002/pssa.202000456
Subject(s) - kesterite , stoichiometry , materials science , nanoscopic scale , phase (matter) , synchrotron , photovoltaic system , solid solution , analytical chemistry (journal) , spectroscopy , band gap , chemical physics , chemical engineering , nanotechnology , optoelectronics , optics , czts , chemistry , metallurgy , ecology , physics , organic chemistry , quantum mechanics , engineering , biology , chromatography
Highly performing kesterite‐based Cu 2 ZnSn(S,Se) 4 (CZTSSe) thin‐film solar cells are typically produced under Cu‐poor and Zn‐rich synthesis conditions. However, these processing routes also facilitate the formation of secondary phases as well as deviations from stoichiometry, causing intrinsic point defects. Herein, the local composition of CZTSSe absorbers prepared with different nominal cation concentrations is investigated by applying energy dispersive X‐ray spectroscopy and synchrotron X‐ray fluorescence spectroscopy at the nanoscale to cross‐sectional lamellae. The findings confirm the formation of ZnS(Se) secondary phases, whose presence, number, and dimension strongly increase with the reduction of the nominal Cu and increment of the nominal Zn content. Furthermore, the local compositions of the CZTSSe phase within the absorber reveal strong variations, leading to collateral and multiple off‐stoichiometry types of the kesterite phase in the absorber, which cause different intrinsic point defects. Therefore, the off‐stoichiometry type determined from the integral composition does not represent the complete true picture of this complex material system. Accordingly, the correlation of integral composition with electrical properties or conversion efficiency may be misleading. Overall, the approach provides new experimental insights into the nanoscale relationship among local compositional fluctuations, off‐stoichiometry types, and secondary phases in these promising photovoltaic materials.