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Performances Enhancement of a‐Si:H Thin Film Photovoltaic Cells by Incorporating Silver Nanoparticles
Author(s) -
Pokam Kuisseu Pauline S.,
Yu Peiqing,
Pingault Timothée,
Blondeau JeanPhilippe,
Ntsoenzok Esidor,
Andreazza Caroline,
Roussel Julien,
Mustapha Elyaakoubi,
Meot Jacques,
Jaffré Alexandre,
Longeaud Christophe
Publication year - 2018
Publication title -
physica status solidi (a)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.532
H-Index - 104
eISSN - 1862-6319
pISSN - 1862-6300
DOI - 10.1002/pssa.201700953
Subject(s) - materials science , surface plasmon resonance , thin film , annealing (glass) , optoelectronics , plasmonic solar cell , surface roughness , absorption (acoustics) , wavelength , substrate (aquarium) , solar cell , light scattering , silver nanoparticle , photovoltaic system , visible spectrum , layer (electronics) , scattering , nanoparticle , optics , nanotechnology , polymer solar cell , composite material , ecology , oceanography , physics , geology , biology
a‐Si:H thin films‐based solar cells offer the benefit of reducing material consumption and fabrication costs. However, such thin absorbing layer reduces the photovoltaic efficiency, due to their poor light absorption at red and near‐infrared wavelengths. Metal NPs such as silver (Ag) can exhibit strong localized surface plasmon (LSP) resonances at different wavelength ranges, allowing increasing the light absorption in the active layer. The goal of this study is to perform an optimal structure of Ag NPs allowing to optimize the light absorption within the a‐Si:H solar cells by means of scattering. Ag layers are deposited on two different SnO 2 substrates (with different roughness). After annealing, quasi‐spherical shaped of Ag NPs with diameters ranging from 10 to 130 nm are obtained. UV‐visible spectroscopy displays one LSP resonance around 560 nm with the less rough substrate, while three LSP resonances around 560, 700, and 850 nm are observed with roughest substrate. These differences are mainly due to the size distribution of NPs and underline the strong influence of the surface roughness and the coupling effect on the NPs behavior. a‐Si:H thin film solar cells with Ag NPs are subsequently elaborated. Spectral response shows an improvement of about 14–15%.